Hydrogen bonding-assisted tautomerization of pyridine moieties in the coordination sphere of an Ir(I) complex.
نویسندگان
چکیده
Ir(I)-induced tautomerization of a pyridine moiety to a carbene in 2,3-bipyridyls has been successfully achieved where an amide group plays a key role as a hydrogen-bonding acceptor and the carbene tautomer is stabilized by both chelation effect and by hydrogen-bonding.
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ورودعنوان ژورنال:
- Chemical communications
دوره 30 شماره
صفحات -
تاریخ انتشار 2008